Product ID:PYREBAN 3 PESTICIDE, 73-80 F-091
MSDS Date:10/25/1993
FSC:6840
NIIN:00N064785
MSDS Number: BZMCX

MIDCO PRODUCTS CO INC

11697 FAIRGROVE IND BLVD
MARYLAND HEIGHTS, MO 63043
US

Emergency Phone: 314-567-1710

Info Phone: 314-567-1710

Preparer: GEORGE LAMB

Cage: 0BTA6

MIDCO PRODUCTS CO INC

MARYLAND HEIGHTS, MO 63043 US

Telephone: 314-567-1710

Cage: 0BTA6

PYRETHRUM; (PYRETHRINS) (CERCLA)

CAS: 8003-34-7

RTECS: UR4200000

Fraction By Weight: 0.05%

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

TOLUENE,

CAS: 51-03-6

RTECS: XS8050000

OSHA PEL N/K

ACGIH TLV: N/K

PHOSPHORODITHIOIC ACID, O,O-DIETHYL

CAS: 2921-88-2

RTECS: TF6300000

Fraction By Weight: 0.55%

OSHA PEL 0.2 MG/M3, S

ACGIH TLV: 0.2 MG/M3, S

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

STODDARD SOLVENT; (MINERAL SPIRITS)

CAS: 8052-41-3

RTECS: WJ8925000

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM

SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC; (MINERAL

CAS: 64742-88-7

OSHA PEL N/K

ACGIH TLV: 100 PPM (MFR)

XYLENE (SARA 313) (CERCLA)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 0.34%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPANE

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

PROPANE, 2-METHYL-; (ISOBUTANE)

CAS: 75-28-5

RTECS: TZ4300000

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: MAY CAUSE SEVERE
IRRITATION, REDNESS, TEARING. SKIN: MAY CAUSE SEVERE IRRITATION,
DEFATTING, DERMATITIS. INGESTION: MAY CAUSE GASTROINTESTINAL
IRRITATION, NAUSEA. INHALATION: LARGE AMOUNT S OF VAPORS MAY CAUSE
NAUSEA OR DIZZINESS. CHRONIC: UNKNOWN, BUT NOT LIKELY TO OCCUR FROM
AEROSOL USE.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:SKIN SENSITIVITY, CHEMICAL
ALLERGIES.

First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. IF IRRITATION
PERSISTS, SEEK MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER.
IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. INGESTION: DO NOT
INDUCE VOMITING. SEEK MEDICAL ATTENTION. INHALATION: REMOVE TO
FRESH AIR. NOTE TO MD: CHLORPYRIFOS IS A CHOLINESTERASE INHIBITOR.
TREAT SYMPTOMATICALLY. ATROPINE IS ANTIDOTAL.

Flash Point Method:TOC
Extinguishing Media:USE CARBON DIOXIDE, STANDARD FOAM, DRY CHEMICAL,
HALON.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EXPOSURE TO TEMPERATURES OVER 120F MAY
CAUSE BURSTING OR VENTING. HEAT OR FIRE MAY CAUSE HAZARDOUS FUMES:
CARBON MONOXIDE.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. DIKE AREA IF POSS
FOR MATL RECOVERY. SMALL QTYS MAY BE ABSORBED W/ABSORB MATLS. TOX
TO FISH. DO NOT DISCHARGE EFFLUENT CONTAINING THIS MATL INTO ANY
BODY OF WATER/INTO SEW ER SYS W/OUT PREVIOUSLY NOTIFYING PROPER
AUTH.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE WHERE TEMPERATURES EXCEED
120F. KEEP OUT OF THE REACH OF CHILDREN.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:NOT REQUIRED. USE NIOSH/MSHA APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:GENERAL VENTILATION RECOMMENDED TO CONTROL THE LEVEL OF
VAPORS.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

Vapor Pres:40PSIG@25C
Vapor Density:>1
Spec Gravity:0.969 (H*2O=1)
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:DISPERSIBLE
Appearance and Odor:WHITE EMULSION, WITH UNPLEASANT ODOR

Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS.
Stability Condition to Avoid:SOURCES OF HEAT.
Hazardous Decomposition Products:OPEN FLAMES MAY PRODUCE CARBON
MONOXIDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.